In nature you have seen flowers and leaves that respond to sunlight. Now an MIT engineer and his German colleagues have created plastics that can be deformed and temporarily fixed into a predetermined shape by light. These programmed materials change shape when exposed to light of wavelengths and return to their original shapes when exposed to light of different wavelengths. The discovery, reported in the April 14 2006 issue of Nature, could have applications in medical and engineering fields.
Plastics with shape-memory--ones that change shape in response to a temperature increase--are well known. Langer and Lendlein reported development of biodegradable versions of these materials in the year 2001. Later, the researchers introduced thermoplastic, biodegradable shape-memory polymers. Now instead of heat they have developed polymers where the shape-memory effect is induced with light. Key to the work: "molecular switches," or photosensitive groups that are grafted onto a permanent polymer network. The resulting photosensitive polymer film is then stretched with an external stress and illuminated with ultraviolet light of a certain wavelength. This prompts the molecular switches to cross link, or bind one to another. The result? When the light is switched off and the external stress released, the cross links remain, maintaining an elongated structure. Exposure to light of another wavelength cleaves the new bonds, allowing the material to spring back to its original shape. It is reported that the temporary shapes are "very stable for long times even when heated to 50 degrees C. An article on this appeared in the April 27, 2005 issue of MIT Tech Talk (Volume 49, Number 25).
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